Synthesis and magnetic property of a nitroxide based on C60 被引量：1

Synthesis and magnetic property of a nitroxide based on C60

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摘要 The compounds containing stable nitroxide radicals possess magnetic properties for the free radical have net magnetic moment. Oxidization of the [60]fulleropyrolidine obtained from the reaction of C60 with diketone and 2-aminoisobutyric acid by m-chloroperoxybenzoic acid gives a new nitroxide integrated with C60. The stable nitroxide based on C60 is confirmed to be antiferro-magnetism with quantum design superconducting quantum interference device (SQUID). The compounds containing stable nitroxide radicals possess magnetic properties for the free radical have net magnetic moment. Oxidization of the [60]fulleropyrolidine obtained from the reaction of C60 with diketone and 2-aminoisobutyric acid bym- chloroperoxybenzoic acid gives a new nitroxide integrated with C60. The stable nitroxide based on C60 is confirmed to be antiferro-magnetism with quantum design superconducting quantum interference device (SQUID).

作者 Zhiqiang Shi Yuliang Li Zhongxin Ge Daoben Zhu

机构地区 Chinese Acad Sci

出处《Chinese Science Bulletin》 SCIE EI CAS 2000年第10期896-899,共4页

关键词 FERROMAGNET FULLERENE NITROXIDE 1 3-dipolar circle ADDITION reaction. ferromagnet fullerene nitroxide 1,3-dipolar circle addition reaction

分类号 O613.71 [理学—无机化学]

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参考文献1

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共引文献2

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同被引文献3

1LI Yuliang, ZHENG Dagui, XU Juhua, MAO Zhong, YANG Jingkui, BAI Fenglian and ZHU DaobenInstitute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.Synthesis of fulleropyrrolidine derivatives of C_(60)[J].Chinese Science Bulletin,1997,42(14):1180-1184. 被引量：3
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引证文献1

1Zhiqiang Shi,Yuliang Li,Shu Wang,Hongjuan Fang,Daoben Zhu.Synthesis and antioxidative properties of polyphenol-fullerenes[J].Chinese Science Bulletin,2001,46(21):1790-1792. 被引量：1

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2000年第10期

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