摘要
Chromium has been identified as a carcinogenic metal. Incineration is the useful method for disposal of toxic chromium hazard waste and a chromium kinetic model in a flame is very important to study chromium oxidation. Chromium chemical kinetics over a range of temperatures of a hydrogen/air flame is proposed. Nine chromium compounds and fifty eight reversible chemical reactions were considered The forward reaction rates are calculated based on the molecular collision approach for unknown ones and Arrhenius’s Law for known ones. The backward reaction rates were calculated according to forward reaction rates, the equilibrium constants and chemical thermodynamics. It is verified by several equilibrium cases and is tested by a hydrogen/air diffusion flame. The results show that the kinetic model could be used in cases in which the chromium kinetics play an important role in a
Chromium has been identified as a carcinogenic metal. Incineration is the useful method for disposal of toxic chromium hazard waste and a chromium kinetic model in a flame is very important to study chromium oxidation. Chromium chemical kinetics over a range of temperatures of a hydrogen/air flame is proposed. Nine chromium compounds and fifty eight reversible chemical reactions were considered The forward reaction rates are calculated based on the molecular collision approach for unknown ones and Arrhenius's Law for known ones. The backward reaction rates were calculated according to forward reaction rates, the equilibrium constants and chemical thermodynamics. It is verified by several equilibrium cases and is tested by a hydrogen/air diffusion flame. The results show that the kinetic model could be used in cases in which the chromium kinetics play an important role in a flame
基金
SupportedbytheBackboneQualifiedScientistsProgrammeofTsinghuaUniversity .
