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Kinetics of Evaporation of Zn and Pb from Carbon-bearing Pellets Made of Dust Containing Zn-Pb-Fe Oxides 被引量:2

Kinetics of Evaporation of Zn and Pb from Carbon-bearing Pellets Made of Dust Containing Zn-Pb-Fe Oxides
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摘要 The influence of reduction temperature, size of coal powder and the carbon content on the evaporation rates of Zn and Pb in pellets made of ZnO-PbO-FeO bearing dust has been investigated between 1100-1300℃. The evaporation rate of Zn and Pb obtained from the experiments has been analyzed with kinetic models. The results show that the control step for evaporation of Zn is reduction reaction of ZnO by CO at the interface,and that the evaporation rate of Pb is controlled by the volatilization of reduction products, i.e. liquid lead. The overall apparent activation energies of Zn and Pb evaporation from the pellet are 79.42kJ/mol and 88.74kJ/mol respectively. The influence of reduction temperature, size of coal powder and the carbon content on the evaporation rates of Zn and Pb in pellets made of ZnO-PbO-FeO bearing dust has been investigated between 1100-1300℃. The evaporation rate of Zn and Pb obtained from the experiments has been analyzed with kinetic models. The results show that the control step for evaporation of Zn is reduction reaction of ZnO by CO at the interface,and that the evaporation rate of Pb is controlled by the volatilization of reduction products, i.e. liquid lead. The overall apparent activation energies of Zn and Pb evaporation from the pellet are 79.42kJ/mol and 88.74kJ/mol respectively.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2000年第3期178-183,共6页 矿物冶金与材料学报(英文版)
关键词 Zn-Pb-bearing dust carbon-containing pellet evaporation kinetics Zn-Pb-bearing dust carbon-containing pellet evaporation kinetics
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参考文献2

  • 1Mansoor M. Hussain,David R. Morris.Reduction of lead minerals by CO/CO2 gas mixtures: Application of the grain model[J].Metallurgical Transactions B.1986(3)
  • 2C. E. Guger,F. S. Manning.Kinetics of zinc oxide reduction with carbon monoxide[J].Metallurgical and Materials Transactions B.1971(11)

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