期刊文献+

Effect of rare earth Eu on anti-passivation of metal oxide anode coating

下载PDF
导出
摘要 The anti passivation effect of metal oxide anode coating doped with rare earth element Eu was discussed. The morphology and the composition distribution of the metal oxide coating anode before and after electrolysis were studied by SEM and EDX analyses. The results show that the erosion of the electrolyte at the defects is the main cause for the failure of the coating. The erosion rate of the electrolyte is anisotropic. In area with high density of defects, the erosion rate is very fast and the failure of the coating is very quick. Moreover, the life time of the coating is prolonged by the doping of Eu. [ The anti-passivation effect of metal oxide anode coating doped with rare earth element Eu was discussed. The morphology and the composition distribution of the metal oxide coating anode before and after electrolysis were studied by SEM and EDX analyses. The results show that the erosion of the electrolyte at the defects is the main cause for the failure of the coating. The erosion rate of the electrolyte is anisotropic. In area with high density of defects, the erosion rate is very fast and the failure of the coating is very quick. Moreover, the life-time of the coating is prolonged by the doping of Eu.
出处 《中国有色金属学会会刊:英文版》 CSCD 2000年第6期717-720,共4页 Transactions of Nonferrous Metals Society of China
基金 Project(59804008)supported by the National Natural Science Foundation of China
  • 相关文献

参考文献9

  • 1Zeitler H U and Hieke E K.Optimization of exposure and development parameter for electron-written PMMA structures. Journal of the Electrochemical Society . 1979
  • 2Koz R and Sucki S.Stabilization of RuO2 by IrO2 for anodic oxygen evolution in acid media. Electrochimica Acta . 1986
  • 3JI Ming-tang,MA Si-de,YANG Fang-ying,et al.RuTi-Mn coating Ti anode used for anodic protection. Chinese Journal of Corrosion and Protection, ( in Chinese) . 1986
  • 4Vercesi G P,Salamin J Y and Comninellis C H.Morphological and microstructural study of the Ti/IrO2-Ta2 O5 electrode: effect of the preparation temperature. Electrochimica Acta . 1991
  • 5Morita M,Iwakura C and Tamura H.The anode characteristics of maganese dioxide electrodes prepared by thermal decomposition of maganese nitrate. Electrochimica Acta . 1977
  • 6Hine F,Yasuda M,Iida T,et al.On the RuO2-TiO2 interlayer of PbO2 electro-deposited Ti anode. Electrochimica Acta . 1984
  • 7Prentice G A and Tobias C W.Deposition and dissolution on sinusoidal electrodes. Journal of the Electrochemical Society . 1982
  • 8Duuigneaud P H and Coussement A.The effect of Chlorine on the formation solid solution in RuO2-TiO2 coating. Industry of Chlorine and Alkaline, (in Chinese) . 1987
  • 9Iwakura Chiaki and Tamura Hideo.The cause of the activity loss of titanium supported ruthenium dioxide electrodes during the anodic evolution of oxygen. Electrical Chemistry and Industrial Physicochemistry . 1980

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部