摘要
Seven kinds of lanthanocene complexes were prepared by the reaction of tridentate Schiff base | N-(2-methoxyphenyl)salicylideneamine with tris(cyclopentadienyl) lanthanide tetrahydrofuranate or bis (cyclopentadienyl) lanthanide chloride tetrahydrofuranate in THF. All the complexes were characterized by MS, EA and IR respectively. The structure of |Cp2LnC14U13NO2) Ln = Sm, Dy, Y, Er| (1–4) was further confirmed by X-ray determination of Cp2Sm(C14H13NO2) (1) which indicates that the complex is monomeric in which central metal is coordinatively saturated by two cyclopentadienyl rings, two oxygens and one nitrogen of the ligand. The isomerization of 1,5-hexadiene explains that complexes (1–4) isomerize this monomer into a mixture of 1,4-hexadiene, 2,4-hexadiene, 1,3-hexadiene, methylenecyclopentane and methyl–cyclopentene. Similarity complexes |CpLn(a) C14 H13NO2) (THF) (Ln=Sm, Dy, Y, Er)| (5–7) polymerize methyl-methacrylate (MMA) to give polyMMA (PMMA) in 51.8% yield and high molecular weight (274 × 103), which shows narrow molecular weight distributions and partially syndiotactic.
Seven kinds of lanthanocene complexes were prepared by the reaction of tridentate Schiff base | N-(2-methoxyphenyl)salicylideneamine with tris(cyclopentadienyl) lanthanide tetrahydrofuranate or bis (cyclopentadienyl) lanthanide chloride tetrahydrofuranate in THF. All the complexes were characterized by MS, EA and IR respectively. The structure of |Cp2LnC14U13NO2) Ln = Sm, Dy, Y, Er| (1–4) was further confirmed by X-ray determination of Cp2Sm(C14H13NO2) (1) which indicates that the complex is monomeric in which central metal is coordinatively saturated by two cyclopentadienyl rings, two oxygens and one nitrogen of the ligand. The isomerization of 1,5-hexadiene explains that complexes (1–4) isomerize this monomer into a mixture of 1,4-hexadiene, 2,4-hexadiene, 1,3-hexadiene, methylenecyclopentane and methyl–cyclopentene. Similarity complexes |CpLn(a) C14 H13NO2) (THF) (Ln=Sm, Dy, Y, Er)| (5–7) polymerize methyl-methacrylate (MMA) to give polyMMA (PMMA) in 51.8% yield and high molecular weight (274 × 103), which shows narrow molecular weight distributions and partially syndiotactic.
基金
Project supported by the National Natural Science Foundation of China (No.29871919) and Sino-Pec (No.29734145)
the State Key Laboratory of Coordination Chemistry, Nanjing University
