Low-valent titanium induced reductive cyclization of nitro compounds and aliphatic ketones:facile synthesis of 3,4-dihydro-(2H) -1,2,4-benzothiadiazine-1,1-dioxides

Low-valent titanium induced reductive cyclization of nitro compounds and aliphatic ketones:facile synthesis of 3,4-dihydro-(2H) -1,2,4-benzothiadiazine-1,1-dioxides

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摘要 The intermolecular reductive cyclization of o-nitrobenzene-sulfonamides with aliphatic ketones induced by TiCl4/Sm system was studied and a series of 3, 3-disubstituted-3,4-dihydro(2H)-1,2, 4-benzothiadiazine-1,1-dioxides were synthesized in moderate to high yields under mild and neutral conditions. The intermolecular reductive cyclization of o-nitrobenzene-sulfonamides with aliphatic ketones induced by TiCl4/Sm system was studied and a series of 3, 3-disubstituted-3,4-dihydro(2H)-1,2, 4-benzothiadiazine-1,1-dioxides were synthesized in moderate to high yields under mild and neutral conditions.

作者钟为慧陈小原张永敏

机构地区 Department of Chemistry Department of Chemistry Department of Chemistry

出处《Chinese Journal of Chemistry》 SCIE CAS CSCD 2000年第5期786-788,共3页 中国化学（英文版）

基金 Project supported by the National Natural Science Foundation of China (No. 29872010) Natural Science Foundation of Zhejiang Province, China

关键词 Nitro compounds KETONES reductive cyclization SAMARIUM titanium tetrachloride Nitro compounds ketones reductive cyclization samarium titanium tetrachloride

分类号 O621.25 [理学—有机化学]

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1.
2McMurry,J. E. Accounts of Chemical Research . 1974
3Werner,L. H.Halamandaris, A.Ricca, S. Jr. Dorfan, L. deStevens, G[].Journal of the American Chemical Society.1960
4Weller,H. N. U.S. 5,378,704 . 1992
5Novello, F.C.,Bell, S.C.,Abrams, L.A.,Ziegler,C,Sprague, J.M. Journal of Organic Chemistry . 1960
6Cragoe, J.E. Jr,Woltersdorf, O.W. Jr,Baer, J.E.,Sprague, J.M. J. Med. Pharm. Chem . 1962
7McMurry,J.E. Accounts of Chemical Research . 1983
8McMurry,J.E. Chemical Reviews . 1989
9Lenoir,D. Synthesis . 1989
10Zhou, L.H.,Zhang, Y.M. Synthetic Communications . 1998

1Da Qing SHI Department of Chemistry,Xuzhou Teachers College,Xuzhou 221009Wei Xing CHEN Department of Chemistry,Nanjing University,Nanjing 210008.LOW-VALENT TITANIUM INDUCED REACTION OF CARBOXYLIC DERIVATIVES WITH NITRO COMPOUNDS[J].Chinese Chemical Letters,1993,4(8):679-680. 被引量：1
2史达清,荣良策,王菊仙,庄启亚,屠树江.A Novel Reductive Cyclization of o-Nitrobenzamides and Ketones Promoted by Low-valent Titanium Reagent[J].Chinese Journal of Chemistry,2004,22(7):743-746.
3Jian Xie CHEN, Da Qing SHI, Wen Ying CHAI, Jian CHEN, Wei Xing CHEN, Tsi Yu KAO Department of Chemistry, Nanjing University, Nanjing, 210008.LOW-VALENT TITANIUM INDUCED REDUCTIVE REACTION OF THIOCYANATES AND ISOCYANATE[J].Chinese Chemical Letters,1993,4(11):943-946.
4Li, HN,Ci, YX.A NEW RAPID FLUOROMETRIC METHOD FOR DETERMINATION OF SULFONAMIDES[J].Chinese Chemical Letters,1995,6(6):495-496.
5Synthesis and Antibacterial Activities of s-Triazole, s-Triazolo[3,4-b]-1,3,4-thiadiazine and s-Triazolo[3,4-b]-1,3-thiadiazole of 5-Methylisoxazole[J].厦门大学学报（自然科学版）,1999,38(S1):478-478.
6ZOUKai-huang,ZHANGLi-xue,ZHANGAn-jiang,LEIXin-xiang,HUANGHui-hua,ZHANGZi-yi.Preparation and Crystal Structure of 3-(2-Hydroxyphenyl)-6-(4-nitrophenyl)-7H- 1,2,4-triazolo[3,4-b][1,3,4 ]thiadiazine[J].Chemical Research in Chinese Universities,2005,21(1):69-72.
7Zhen Nian HUANG,Sheng JIN,Mei Gong FAN(State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, 2 Department ofChemistry, Peking University, Beijing 100871, 3. Institute of Photographic Chemistry, Academ Sciences Sinica Bei.The Intramolecular Coupling Reaction of 1,6-Bis(1-Alky1-2-Methylindol-3-yl)hexane-1,6-dione Induced by Low-valent Titanium[J].Chinese Chemical Letters,1997,8(1):7-8.
8Wei Xing CHEN,Jian Xie CHEN,Jian Ping JIANG,Tsi Yu KAO.LOW-VALENT TITANIUM INDUCED REDUCTIVE COUPLING OF AROMATIC NTTRILES TO 1,2-ARYLETHANONES[J].Chinese Chemical Letters,1991,2(5):351-352.
9Guo Feng ZHAO,Hua Zheng YANG(Institute of Elemento-Organic Chemistry Nankai University, Tianjin 300071).The　Synthesis　and　Biological　Activity　of　N－Arylamino　Carbonyl　Methylene　1，2－Benzothiazine　1，1－Dioxides[J].Chinese Chemical Letters,1996,7(12):1087-1088.
10SHI Da-Qing,SHI Chun-Ling,RONG Liang-Ce.Synthesis and Crystal Structure of 1-(4-Chlorophenyl)-2-cyano-3-amino-3a-hydroxy- 3a,3b,6,7-tetrahydrobenzo[4,5]indene[J].Chinese Journal of Structural Chemistry,2005,24(12):1393-1396.

Chinese Journal of Chemistry

2000年第5期

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Low-valent titanium induced reductive cyclization of nitro compounds and aliphatic ketones:facile synthesis of 3,4-dihydro-(2H) -1,2,4-benzothiadiazine-1,1-dioxides

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