摘要
A new strategy for the synthesis of unsymmetrical phosphotriesters was reported: an alcohol was converted to unsymmetrical dialkyl phosphites firstly, which then reacted with the second alcohol or phenol to afford required unsymmetrical triesters in the presence of iodine in high yields under exceptionally mild conditions.
A new strategy for the synthesis of unsymmetrical phosphotriesters was reported: an alcohol was converted to unsymmetrical dialkyl phosphites firstly, which then reacted with the second alcohol or phenol to afford required unsymmetrical triesters in the presence of iodine in high yields under exceptionally mild conditions.
基金
Project supported by the National Natural Science Foundation of China (No. 29772047).
