摘要
Bis-perfluoroalkylation of aromatic compounds such as dimethoxybenzenes (2, 4, 6), anisole (8), pyridine (10) and quinoline (13) was accomplished by reaction with excess sodium perfluoroalkanesulfinates, RFSO2Na (1), in the presence of Mn(OAc)3·2H2O under mild conditions. The reaction provides a facile method for the synthesis of bis-perfluoroalkylated aromatic compounds.
Bis-perfluoroalkylation of aromatic compounds such as dimethoxybenzenes (2, 4, 6), anisole (8), pyridine (10) and quinoline (13) was accomplished by reaction with excess sodium perfluoroalkanesulfinates, RFSO2Na (1), in the presence of Mn(OAc)3·2H2O under mild conditions. The reaction provides a facile method for the synthesis of bis-perfluoroalkylated aromatic compounds.
基金
Project supported by the National Natural Science Foundation China (Nos. 29772041 and 29632003).
