A new class of chiral pyrrolidine ligands for homogeneous catalytic enantioselective cyclopropanation of styrene

A new class of chiral pyrrolidine ligands for homogeneous catalytic enantioselective cyclopropanation of styrene

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摘要 A new class of chiral pyrrolidine ligands have been successfully synthesized and their chiral induction abilities have been examined in the homogeneous catalytic enantioselective cyclopropanation of styrene. 15–30% enantiomeric excess (ee) has been achieved. A new class of chiral pyrrolidine ligands have been successfully synthesized and their chiral induction abilities have been examined in the homogeneous catalytic enantioselective cyclopropanation of styrene. 15–30% enantiomeric excess (ee) has been achieved.

作者施敏蒋建康

机构地区 Laboratory of Organometallic Chemistry

出处《Chinese Journal of Chemistry》 SCIE CAS CSCD 2000年第3期407-410,共4页 中国化学（英文版）

基金 Project supported by the National Natural Science Foundation of China (NO. 29790120) and Chinese Academy of Sciences (No.KJ951-A1-506-04).

关键词 Chiral ligand PYRROLIDINE ENANTIOSELECTIVE CYCLOPROPANATION catalyst Chiral ligand pyrrolidine enantioselective cyclopropanation catalyst

分类号 O643.3 [理学—物理化学]

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Chinese Journal of Chemistry

2000年第3期

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A new class of chiral pyrrolidine ligands for homogeneous catalytic enantioselective cyclopropanation of styrene

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