摘要
Methyl methacrylate (MMA) was effectively polymerized by diphenylamido bis(methylcyclopentadienyl) ytterbium complex (MeCp)2 YbNPh2 (THF). The reaction can be carried out over a range of polymerization temperature from - 40°C to 40°C and gives me polyMMA with high molecular weights. The initiation mechanism was demonstrated by diphenylamido-terminated methyl methacrylate oligomer.
Methyl methacrylate (MMA) was effectively polymerized by diphenylamido bis(methylcyclopentadienyl) ytterbium complex (MeCp)2 YbNPh2 (THF). The reaction can be carried out over a range of polymerization temperature from - 40°C to 40°C and gives me polyMMA with high molecular weights. The initiation mechanism was demonstrated by diphenylamido-terminated methyl methacrylate oligomer.
基金
Project supported by the National Natural Science Foundation of China, the Natural Science Foundation of Jiangsu Province and Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.
