期刊文献+

Application of Thermogravimetry to Study the Kinetics and Stability of Porphyrin Copper-sodium of Ephedra

Application of Thermogravimetry to Study the Kinetics and Stability of Porphyrin Copper-sodium of Ephedra
下载PDF
导出
摘要 Thermogravimetry was used to study the non-isothermal decomposition kinetics and the stability of porphyrin copper-sodium from ephedra. The kinetic equation for the second step can be expressed as . The kinetic compensation effect is found to be: InA=0. 2468E a ?8. 0513.Ea is 206. 61 kJ/mol. The results show that porphyrin copper-sodium has a high activation energy and good stability. Thermogravimetry was used to study the non-isothermal decomposition kinetics and the stability of porphyrin copper-sodium from ephedra. The kinetic equation for the second step can be expressed as . The kinetic compensation effect is found to be: InA=0. 2468E a ?8. 0513.Ea is 206. 61 kJ/mol. The results show that porphyrin copper-sodium has a high activation energy and good stability.
出处 《Wuhan University Journal of Natural Sciences》 EI CAS 2000年第3期357-360,共4页 武汉大学学报(自然科学英文版)
关键词 porphyrin copper-sodium TG-DTG activation energy non-isothermal kinetics porphyrin copper-sodium TG-DTG activation energy non-isothermal kinetics
  • 相关文献

参考文献1

二级参考文献6

  • 1Brown G M,Hopf F R,Ferguson J A,et al.Metalloporphyrin redox chemistry: The effect of extraplanarligands on the site of oxidation in ruthenium porphyrins. Journal of the American Chemical Society . 1973
  • 2Boschi T,Bontempelli G,Mazzocchin G-A.Synthesisand electrochemical behavior of novel ruthenium(Ⅱ) tetraphenyl porphinate derivatives. Inorganica Chimica Acta . 1979
  • 3Rillema D P,Nagle J K,Barringer L F,et al.Redoxproperties of metalloporphyrin excited states, lifetimes,and related properties of a series of parasubstituted tetraphenylporphine carbonyl complexes of ruthenium(Ⅱ). Journal of the American Chemical Society . 1981
  • 4Che C M,Leung W H,Chung W C.Novel osmium(Ⅳ)and - (Ⅴ) porphyrins: Synthesis, spectroscopy andelectrochemistry. Inorganic Chemistry . 1990
  • 5Li Zaoying,Che Chiming.Bis (aliphatic amine) ruthenium (Ⅱ) porphyrins synthesis, spectroscopy and crystalstructure. Journal of Inorganic Chemistry USSR . 1997
  • 6Mosseri S,Neta P.Redox reactions of osmium porphyrins. Journal of the Chemical Society Dalton Transactions . 1988

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部