摘要
The cyclic voltammetry, currenttime curve at potential step and constant current method were used to investigate the electrochemical behaviour of nickel chloride on the Pt eletrodes in N,Ndimethylformamide (DMF). The experimental results indicate that the reduction of Ni() is irreversible in two steps, first Ni(solvent)n]()+2e (0) and then is reduced to the metal. The transfer coefficient and diffusion coefficient of Ni() in DMF were also determined.
The cyclic voltammetry, currenttime curve at potential step and constant current method were used to investigate the electrochemical behaviour of nickel chloride on the Pt eletrodes in N,Ndimethylformamide (DMF). The experimental results indicate that the reduction of Ni() is irreversible in two steps, first Ni(solvent)n]()+2e (0) and then is reduced to the metal. The transfer coefficient and diffusion coefficient of Ni() in DMF were also determined.
