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Study on Extracting Low Concentration Cadmium from Zinc Hydrometallurgy System by Liquid Membrane Crystallizing Technique

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摘要 The extraction of low concentration cadmium from a system containing high concentration zinc was studied and got CdS product directly. A new liquid membrane system taking DIPSA, TIBPS as carriers, (NH 4) 2S as precipitating agent was reported. Precipitating Cd 2+ in the internal aq. phase that is used to treat sulfuric acid leaching solution of zinc oxide in zinc hydrometallurgy has gotten satisfied results of extracting cadmium from high concentration zinc. After one stage of batch process under the optimum liquid membrane conditions, 98.6% transferring rate and 98.1% extracting rate of cadmium was obtained with only less than 1.0% transferring rate of zinc, and the feed solution can be purified very well. The extraction of low concentration cadmium from a system containing high concentration zinc was studied and got CdS product directly. A new liquid membrane system taking DIPSA, TIBPS as carriers, (NH 4) 2S as precipitating agent was reported. Precipitating Cd 2+ in the internal aq. phase that is used to treat sulfuric acid leaching solution of zinc oxide in zinc hydrometallurgy has gotten satisfied results of extracting cadmium from high concentration zinc. After one stage of batch process under the optimum liquid membrane conditions, 98.6% transferring rate and 98.1% extracting rate of cadmium was obtained with only less than 1.0% transferring rate of zinc, and the feed solution can be purified very well.
作者 汤兵 石太宏
出处 《Rare Metals》 SCIE EI CAS CSCD 1999年第1期49-55,共7页 稀有金属(英文版)
关键词 EXTRACTION CADMIUM Zinc hydrometallurgy Liquid membrane CRYSTALLIZATION Extraction, Cadmium, Zinc hydrometallurgy, Liquid membrane, Crystallization
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