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Synthesis and Structural Characterization of Adduct [La(NO_3)_3·4H_2O]·2(BQEB)

Synthesis and Structural Characterization of Adduct [La(NO_3)_3·4H_2O]·2(BQEB)
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摘要 A new podand compound o-Bis(8'-quinolyloxy) ethylenoxyl benzene (BQEB) was prepared. A lanthanum adduct with BQEB was spothesized and its structure was characterized by X-ray crystal analysis. The La(III) is ten-coordinated to the three No3- and four H2O. Two podand molecules are linked to the coordination core by four hydrogen bonds. The crystal is packed in the manner of .LLMLLMLL. A new podand compound o-Bis(8'-quinolyloxy) ethylenoxyl benzene (BQEB) was prepared. A lanthanum adduct with BQEB was spothesized and its structure was characterized by X-ray crystal analysis. The La(III) is ten-coordinated to the three No3- and four H2O. Two podand molecules are linked to the coordination core by four hydrogen bonds. The crystal is packed in the manner of .LLMLLMLL.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1998年第8期783-784,共2页 中国化学快报(英文版)
关键词 PODAND lanthanum adduct crystal structure podand lanthanum adduct crystal structure
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