Photoinduced Electron Transfer Reaction between N,N-Dimethylaniline and 7,7-Dichloronorcarane

Photoinduced Electron Transfer Reaction between N,N-Dimethylaniline and 7,7-Dichloronorcarane

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摘要 U.V. irradiation of N,N-dimethylaniline (DMA) in the presence of 7,7-dichloronorcarane (DCN) in acetonitrile solution produces N-methyianiline, 4,4'-methylenebis-(N,N-dimethylaniline), N-(4'-N',N'-dimethylaminobenzyl)-N-methylaniline and 7-chloronorcarane as the major products. A photoinduced electron transfer mechanism is proposed. U.V. irradiation of N,N-dimethylaniline (DMA) in the presence of 7,7-dichloronorcarane (DCN) in acetonitrile solution produces N-methyianiline, 4,4'-methylenebis-(N,N-dimethylaniline), N-(4'-N',N'-dimethylaminobenzyl)-N-methylaniline and 7-chloronorcarane as the major products. A photoinduced electron transfer mechanism is proposed.

作者 Zhang, W Yang, L Wu, LM Liu, YC Liu, ZL

机构地区 Lanzhou Univ

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1998年第6期509-512,共4页 中国化学快报（英文版）

关键词 photoinduced electron transfer dimethylaniline dichloronorcarane photoinduced electron transfer dimethylaniline dichloronorcarane

分类号 O644 [理学—物理化学]

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Chinese Chemical Letters

1998年第6期

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Photoinduced Electron Transfer Reaction between N,N-Dimethylaniline and 7,7-Dichloronorcarane

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