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Total Synthesis of (±)Chrysotricine

Total Synthesis of (±)Chrysotricine
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摘要 (±)Chrysotricine 1 was synthesized by a facile route. The key steps in the synthesis were aldol condensation of dilithium salt of harman 4 with 6 -methyl-5-hepten-2-one 5 and cyclization of compound 6 using MCPBA. The 1HNMR specmim of synthetic product was identical to that of the natural sample. (±)Chrysotricine 1 was synthesized by a facile route. The key steps in the synthesis were aldol condensation of dilithium salt of harman 4 with 6 -methyl-5-hepten-2-one 5 and cyclization of compound 6 using MCPBA. The 1HNMR specmim of synthetic product was identical to that of the natural sample.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1998年第4期357-360,共4页 中国化学快报(英文版)
关键词 (±)chrysotricine aldol condensation dilithium salt of harman (±)chrysotricine, aldol condensation, dilithium salt of harman
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