摘要
A tetranuclear complex [Co(III)(2)(L)(2)(AcO)(2)(OH)](AcO)(2I). 4H(2)O (L = N-ferrocenylmethyl-1,4,7-triaza-cyclononane) was prepared from ligand L . HI and its crystal structure was determined. The crystal exists in P2(1)(/)a space group and its cell parameters are a = 14.285(3)Angstrom, b = 19.888(3)Angstrom, c = 19.133(3)Angstrom; beta = 109.12(2)degrees; V = 5135.8 Angstrom(3); Z = 4. Electrochemical investigation reveals that the oxidation potential of ferrocenyl group in 1 has a 0.11V-positive-shift from that of the ferrocenyl group in L.HI.
A tetranuclear complex [Co(III)(2)(L)(2)(AcO)(2)(OH)](AcO)(2I). 4H(2)O (L = N-ferrocenylmethyl-1,4,7-triaza-cyclononane) was prepared from ligand L . HI and its crystal structure was determined. The crystal exists in P2(1)(/)a space group and its cell parameters are a = 14.285(3)Angstrom, b = 19.888(3)Angstrom, c = 19.133(3)Angstrom; beta = 109.12(2)degrees; V = 5135.8 Angstrom(3); Z = 4. Electrochemical investigation reveals that the oxidation potential of ferrocenyl group in 1 has a 0.11V-positive-shift from that of the ferrocenyl group in L.HI.
