Samarium diiodide induced asymmetric synthesis of γ-butyrolactone using chiral auxiliaries derived from isosorbide and isomannide

Samarium diiodide induced asymmetric synthesis of γ-butyrolactone using chiral auxiliaries derived from isosorbide and isomannide

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摘要 The asymmetric reductive coupling reaction of various acrylates derived from D-isosorbide and D-isomannide with acetophenone mediated by samarium diiodide to give both enantiomers of the optically active γ-butyrolactone was described. The best enantiomeric excess of the products was 60%. The asymmetric reductive coupling reaction of various acrylates derived from D-isosorbide and D-isomannide with acetophenone mediated by samarium diiodide to give both enantiomers of the optically active γ-butyrolactone was described. The best enantiomeric excess of the products was 60%.

作者徐明华林国强夏立钧

机构地区 Shanghai Institute of Organic Chemistry

出处《Chinese Journal of Chemistry》 SCIE CAS CSCD 1998年第6期561-564,共0页 中国化学（英文版）

基金 Project (No. 297912045) supported by the National Natural Science Foundation of China

关键词 Asymmetry Γ-BUTYROLACTONE ISOSORBIDE ISOMANNIDE samarium diiodide Asymmetry γ-butyrolactone isosorbide isomannide samarium diiodide

分类号 O627 [理学—有机化学]

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Chinese Journal of Chemistry

1998年第6期

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Samarium diiodide induced asymmetric synthesis of γ-butyrolactone using chiral auxiliaries derived from isosorbide and isomannide

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