炸药的热分解——等温和非等温数据的对比

Thermal Decomposition of Explosives — A Comparation of Data, Obtained by Isothermal and Nonisothermal (DTA) Technique

对某些炸药的等温和非等温的热分解动力学数据进行了比较。对于那些热分解速率相对较慢、蒸发较快的样品，由等温方法和非等温方法得到的数据区别较大，而进行固相分解、且热分解速率较快的样品，二者区别规律性不大。对这一现象原因进行了分析。

A comparation has been made for kinetic data of thermal decomposition of explosives, obtained by isothermal and nonisothermal technique. For samples, which decompose relatively slow and evaporate quickly, the difference between data, obtained by iso and nonisothermal technique is great,for samples, which decompose in solid state and more quickly, the difference of data is not regular. The reason of these phenomena has been analysed.