Chemistry of Taxoid Sinenxan A: (Ⅰ) Epimerization of the 14β-hydroxyl Group
Chemistry of Taxoid Sinenxau A:(Ⅰ) Epimerization of the 14β-hydroxyl Group
摘要
Compound 2 with 14β-hydroxyl group was successfully converted into its epimerized α-counterpart via oxidation - reduction.The elimination product (6) was auto-oxidized to epoxide 8,even in the solid state
Compound 2 with 14β-hydroxyl group was successfully converted into its epimerized α-counterpart via oxidation - reduction.The elimination product (6) was auto-oxidized to epoxide 8,even in the solid state
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