摘要
Synthesis of five 7-membered compounds containing silane, sulfur and phosphorus groups was achieved by using endo, endo-bicyclo[3.3.0]octanediol 2. These tricyclic molecules are considered as ideal substrates far kinetic resolution of the diol. A discussion of the spectral data about these compounds was given and four of them would be substrate molecules containing an sp(3) hybridized prochiral center and could be used for molecules for a kinetic resolution combining configurational diastereotopos-differentiating and diastereoisomer-differentiating reactions.
Synthesis of five 7-membered compounds containing silane, sulfur and phosphorus groups was achieved by using endo, endo-bicyclo[3.3.0]octanediol 2. These tricyclic molecules are considered as ideal substrates far kinetic resolution of the diol. A discussion of the spectral data about these compounds was given and four of them would be substrate molecules containing an sp(3) hybridized prochiral center and could be used for molecules for a kinetic resolution combining configurational diastereotopos-differentiating and diastereoisomer-differentiating reactions.
