Molecular and Crystal Structure of Hexacobalt Carbonyl Cluster Containg Twin Co_3S(CO)_7 Fragments Linked by a Novel Phosphido-Thiolato Ligand as Backbone

Molecular and Crystal Structure of Hexacobalt Carbonyl Cluster Containg Twin Co_3S(CO)_7 Fragments Linkedby a Novel Phosphido-Thiolato Ligand as Backbone

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摘要 Reaction of dimers of (R) thionophosphine sulfide (R = P - C6H4OMe,SMe ) with Co, (CO), yields the novel hexacobalt cluster [Co'(μ3, -S)2, (CO) 14 (μ4 -μ4- and the trinuclear clusterPSCH,)J 2' In 1, tw0 Co3S(C0)7 units linked by a novel phosphido-thio1ato bifunc-tiona1 bridging p'-SPR ligand as backbone. Reaction of dimers of (R) thionophosphine sulfide (R = P - C6H4OMe,SMe ) with Co, (CO), yields the novel hexacobalt cluster [Co'(μ3, -S)2, (CO) 14 (μ4 -μ4- and the trinuclear clusterPSCH,)J 2' In 1, tw0 Co3S(C0)7 units linked by a novel phosphido-thio1ato bifunc-tiona1 bridging p'-SPR ligand as backbone.

作者 Zhi Rong ZHAO Xiang HU Shu Tang LIU and Qi Wang LIU(Department of Chedristry, Inner Mongolia University, Huhhot 010021)

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1997年第5期461-464,共4页 中国化学快报（英文版）

分类号 O614 [理学—无机化学]

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Chinese Chemical Letters

1997年第5期

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Molecular and Crystal Structure of Hexacobalt Carbonyl Cluster Containg Twin Co_3S(CO)_7 Fragments Linked by a Novel Phosphido-Thiolato Ligand as Backbone

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