摘要
Using the reaction of Ar(3Po,2) + PCl3 as a source of PCl(b1 +), we have measured the quenching rate constants of PCl(b,v'=0) for more than 20 quenchers. The E-V model is used to calculate the rate constants. The comparison of the calculated values with the experimental ones shows that the quenching of PCl(b) by the reagent molecules results from the electronic to vi-brational energy near resonance transfer and has been related to the Franck-Condon factors for the PCl(b,v'=0-a,v'=m) transition and to the anharmonicities of the terminal bonds of the quenchers. In addition, the influence of the polarizability of the reagent molecule on the quenching rate constant is discussed.
Using the reaction of Ar(3Po,2) + PCl3 as a source of PCl(b1 +), we have measured the quenching rate constants of PCl(b,v'=0) for more than 20 quenchers. The E-V model is used to calculate the rate constants. The comparison of the calculated values with the experimental ones shows that the quenching of PCl(b) by the reagent molecules results from the electronic to vi-brational energy near resonance transfer and has been related to the Franck-Condon factors for the PCl(b,v'=0-a,v'=m) transition and to the anharmonicities of the terminal bonds of the quenchers. In addition, the influence of the polarizability of the reagent molecule on the quenching rate constant is discussed.
作者
LIU, Chuan-Pu ZOU, Sheng-Li GUO, Jing-Zhong GU, Yue-ShuDepartment of Chemistry, Shandong University, Jinan, Shandong 250100, ChinaCHU, Yan-Nan CAO, De-ZhaoLaser Spectroscopy Laboratory, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei, Anhui 230031, China
基金
Project supported by the National Natural Science Foundation of China and by the Cross-Century Talent Foundation of Shandong University.
