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Room temperature phosphorescence of α-bromonaphthalene induced by β-cyclodextrin in the presence of cyclohexane 被引量:1

Room temperature phosphorescence of α-bromonaphthalene induced by β-cyclodextrin in the presence of cyclohexane
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摘要 β-Cyclodextrin (β-CD) can induce a-bromonaphthalene (BrN) to emit strong room temperature phosphorescence (RTP) in the presence of micro amounts of cyclohexane (c-hexane). Experiments of luminescence spectra, phosphorescence lifetime and fluorescence polarization prove the formation of c-hexane/β-CD/BrN ternary inclusion complex. The apparent formation constant of the ternary inclusion complex was determined and the effect mechanism of c-hexane on the RTP of BrN induced by β-CD is discussed. β-Cyclodextrin (β-CD) can induce a-bromonaphthalene (BrN) to emit strong room temperature phosphorescence (RTP) in the presence of micro amounts of cyclohexane (c-hexane). Experiments of luminescence spectra, phosphorescence lifetime and fluorescence polarization prove the formation of c-hexane/β-CD/BrN ternary inclusion complex. The apparent formation constant of the ternary inclusion complex was determined and the effect mechanism of c-hexane on the RTP of BrN induced by β-CD is discussed.
出处 《Science China Chemistry》 SCIE EI CAS 1996年第4期416-424,共9页 中国科学(化学英文版)
关键词 cyclodextrin CYCLOHEXANE α-bromonaphthalene room temperature phosphorescence. cyclodextrin, cyclohexane, α-bromonaphthalene, room temperature phosphorescence.
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