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Transient species of fullerenes studied with pulse radiolysis and laser photolysis 被引量:1

Transient species of fullerenes studied with pulse radiolysis and laser photolysis
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摘要 The excited triplet of C60 or C70 is generated via either direct excitation by laser light or energy transfer from excited states of solvent to C60 and C70. The cation radical of C60 is produced either via hole transfer from cation radical of CCl4 to C60 or via electron transfer from excited triplet of C60 to CCl4. C60 and C70 could be added to trichloromethyl radical to produce adduct radicals with different mechanisms. The excited triplet of C60 or C70 is generated via either direct excitation by laser light or energy transfer from excited states of solvent to C60 and C70. The cation radical of C60 is produced either via hole transfer from cation radical of CCl4 to C60 or via electron transfer from excited triplet of C60 to CCl4. C60 and C70 could be added to trichloromethyl radical to produce adduct radicals with different mechanisms.
出处 《Science China Chemistry》 SCIE EI CAS 1996年第6期561-567,共7页 中国科学(化学英文版)
关键词 FULLERENE pulse RADIOLYSIS laser PHOTOLYSIS TRIPLET radical. fullerene, pulse radiolysis, laser photolysis, triplet, radical.
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  • 5Steenken S,Warren C J,Gilbert B C.Generation of radical-cations from naphthalene and some derivatives, both by photoionization and reaction with SO4-: formation and reactions studied by laser flash photolysis. J. Chem. Soc. Perkin Trans. 2 . 1990
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  • 7Jin,C .Y,Zhang,D .D,Oguma,T .etal.Studiesonnovelcyclodextrins:inclusionofC60 andC70,J.InclusionPhe nom. Mol.Recognit.Chem . 1996
  • 8Tokuyama,H,Yamago,S,Nakamura,E .etal.Photoinducedbiochemicalactivityoffullerenecarboxylicacid. J .Am.Chem.Soc . 1993
  • 9Sijbesma,R,Srdanov,G,Wudl,F .etal.SynthesisofafullerenederivativefortheinhibitionofHIVenzymes. J .Am.Chem.Soc . 1993
  • 10Chiang,L .Y,Wang,L .Y,Swirczewski,J .W .etal.Efficientsynthesisofpolyhydroxylatedfullerenederivativesviahy drolysisofpolycyclo sulfatedprecursors. Journal of Organic Chemistry . 1994

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