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INFLUENCES OF WATER-SOLUBLE CATIONIC MONOMERS ON THE POLYMERIZATION RATE IN THE INVERSE EMULSION

INFLUENCES OF WATER-SOLUBLE CATIONIC MONOMERS ON THE POLYMERIZATION RATE IN THE INVERSE EMULSION
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摘要 This investigation deals with the free radical polymerization both of (2-methacryloyloxyethyl) trimethyl ammonium chloride (QACEMA) and of diallyldimethyl ammonium chloride (DADMAC) in inverse emulsion. The influences of some factors, such as the concentration of monomers, initiator and emulsifier are discussed. The polymerization rate equations of above two monomers can be written as follows: R(p) = k[M](1.21)[I](0.82)[E](0.57) (for QACEMA) R(p) = k'[M](1.34)[I](0.90)[E](0.62) (for DADMAC) This investigation deals with the free radical polymerization both of (2-methacryloyloxyethyl) trimethyl ammonium chloride (QACEMA) and of diallyldimethyl ammonium chloride (DADMAC) in inverse emulsion. The influences of some factors, such as the concentration of monomers, initiator and emulsifier are discussed. The polymerization rate equations of above two monomers can be written as follows: R(p) = k[M](1.21)[I](0.82)[E](0.57) (for QACEMA) R(p) = k'[M](1.34)[I](0.90)[E](0.62) (for DADMAC)
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1996年第2期183-187,共5页 高分子科学(英文版)
基金 This project is supported by Tianjin Science Foundation for Youths.
关键词 (2-methacryloyloxyethyl)trimethyl ammonium chloride diallyldimethyl ammonium chloride polymerization rate inverse emulsion (2-methacryloyloxyethyl)trimethyl ammonium chloride diallyldimethyl ammonium chloride polymerization rate inverse emulsion
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