摘要
This investigation deals with the free radical polymerization both of (2-methacryloyloxyethyl) trimethyl ammonium chloride (QACEMA) and of diallyldimethyl ammonium chloride (DADMAC) in inverse emulsion. The influences of some factors, such as the concentration of monomers, initiator and emulsifier are discussed. The polymerization rate equations of above two monomers can be written as follows: R(p) = k[M](1.21)[I](0.82)[E](0.57) (for QACEMA) R(p) = k'[M](1.34)[I](0.90)[E](0.62) (for DADMAC)
This investigation deals with the free radical polymerization both of (2-methacryloyloxyethyl) trimethyl ammonium chloride (QACEMA) and of diallyldimethyl ammonium chloride (DADMAC) in inverse emulsion. The influences of some factors, such as the concentration of monomers, initiator and emulsifier are discussed. The polymerization rate equations of above two monomers can be written as follows: R(p) = k[M](1.21)[I](0.82)[E](0.57) (for QACEMA) R(p) = k'[M](1.34)[I](0.90)[E](0.62) (for DADMAC)
基金
This project is supported by Tianjin Science Foundation for Youths.