摘要
在汞盐和硝基苯磺酸存在下，用硝酸硝化甲苯，获得了对位异构体含量较高的－硝基甲苯，对位体和邻位体的比值（ｐ／ｏ＝２．４１）明显高于汞盐负载在Ｎａｆｉｏｎ－Ｈ上的催化硝化结果（ｐ／ｏ＝１．８１）。探讨了汞盐和硝基苯磺酸催化甲苯硝化机理。
The nitration of toluene with nitric acid catalyzed by mercury (Ⅱ) salt and nitro benzene sulfonic acids gave mononitrotoluene of the high para-isomer content. The para:ortho ratio (2.40) was higher than that of mercury (Ⅱ)-promoted nitration of toluene over Nafion-H catalyst (1.81). The mechanisms of the catalytic nitration of toluene were discussed.
出处
《辽宁石油化工大学学报》
CAS
1995年第3期12-15,共4页
Journal of Liaoning Petrochemical University
关键词
甲苯
硝基化
硝基苯磺酸
Methylbenzene
Nitration
Nitrobenzene sulfonic acid
