Co（Ⅱ）、Ni（Ⅱ）与三聚硫氰酸的配合物及其衍生物的合成研究（Ⅱ）

Synthesis and characteterization of Cytlotrithiocyanates complexes of Co(Ⅱ)and Ni(Ⅱ)

本文用Ｃｏ（Ⅱ）、Ｎｉ（Ⅱ）与三聚硫氰酸配合物与邻二氨基苯反应，得到两个新的化合物，经ＩＲ、Ｕｖ、元素分析等表征研究，指认它们是Ｎａ＿３｛Ｍ（Ｃ＿３Ｎ＿３Ｓ＿３）［Ｐｈ（ＮＨ＿２）＿２］Ｃｌ＿２｝（Ｍ）─Ｃｏ、Ｎｉ）．

The reaction of CoCl_2 6H_2O with C_3N_3S_3Na_3 in Me_2SO yields the Na_3[M(Me_2So)(C_3N_3S_3)Cl_2(Ⅰ),The reaction of(Ⅰ) with Ph(NH_2)_2 results in Na_3 {M(C_3N_3S_3)([Ph(NH_2)_2])Cl_2}(M─Co、Ni)that has been characterized by elemental analysis、IR and U-Vspectra.