Studies　on　Solid　State　Reactions　of　Coordination　Compounds（LXXI）──Solid　State　Reactions　of　o－Aminobenzoic　Acid　with　Copper（Ⅱ）　Acetate　and　Formate　at　Room　Temperature

Studies on Solid State Reactions of Coordination Compounds (LXXI)──Solid State Reactions of o-Aminobenzoic Acid withCopper (Ⅱ) Acetate and Formate at Room Temperature

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摘要 olid state reactions of o-aminobenzoic acid (HOAB) with Cu (OAc)_2·H_2O,Cu(HCOO)_2 · 4H_2O, anhydrous Cu (OAc)_2 and Cu (HCOO)_2 at room or close toroom temperature have been investigated. The product Cu(OAB)_2 with a high yieldwas synthesized very conveniently compared witb the solution phase method. Thekinetic behavior was studied by means of the isothermal electrical conductivity mea-surement. The reactivity was found to decrease in the order : Cu(OAc)_2· H_2O>Cu(OAc)_2>Cu (HCOO)_2 ·4H_2O>Cu (HCOO)_2, which was attributable to the crystalstructures of the copper salts. olid state reactions of o-aminobenzoic acid (HOAB) with Cu (OAc)_2·H_2O,Cu(HCOO)_2 · 4H_2O, anhydrous Cu (OAc)_2 and Cu (HCOO)_2 at room or close toroom temperature have been investigated. The product Cu(OAB)_2 with a high yieldwas synthesized very conveniently compared witb the solution phase method. Thekinetic behavior was studied by means of the isothermal electrical conductivity mea-surement. The reactivity was found to decrease in the order : Cu(OAc)_2· H_2O>Cu(OAc)_2>Cu (HCOO)_2 ·4H_2O>Cu (HCOO)_2, which was attributable to the crystalstructures of the copper salts.

作者 ZHENG Li-min LIN Jian-jun FU Yan and XIN Xin-quan (Department of Chemistry , Manjing University , Naiijing , 210008)

出处《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1995年第1期45-49,共5页 高等学校化学研究（英文版）

关键词 Solid state reaction o-Aminobenzoic acid Copper acetate Copper formate Electrical conductivity Solid state reaction, o-Aminobenzoic acid , Copper acetate, Copper formate , Electrical conductivity

分类号 O621.25 [理学—有机化学]

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Chemical Research in Chinese Universities

1995年第1期

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Studies　on　Solid　State　Reactions　of　Coordination　Compounds（LXXI）──Solid　State　Reactions　of　o－Aminobenzoic　Acid　with　Copper（Ⅱ）　Acetate　and　Formate　at　Room　Temperature

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Studies on Solid State Reactions of Coordination Compounds（LXXI）──Solid State Reactions of o－Aminobenzoic Acid with Copper（Ⅱ） Acetate and Formate at Room Temperature

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Studies　on　Solid　State　Reactions　of　Coordination　Compounds（LXXI）──Solid　State　Reactions　of　o－Aminobenzoic　Acid　with　Copper（Ⅱ）　Acetate　and　Formate　at　Room　Temperature