摘要
Two dicoprer(I) complexes as model compounds for hemocyanin were prepared and characterized by clemental analyses, IR, 1H NMR spectra and other means. UV- VIS spectra indicate that the solutions of complexes in DMF can reversibly combine with dioxygen. Oxygenation ratio 2: 1(Cu: O2) was proved through manometric oxygen-uptake measurements.
Two dicoprer(I) complexes as model compounds for hemocyanin were prepared and characterized by clemental analyses, IR, 1H NMR spectra and other means. UV- VIS spectra indicate that the solutions of complexes in DMF can reversibly combine with dioxygen. Oxygenation ratio 2: 1(Cu: O2) was proved through manometric oxygen-uptake measurements.