THE REARRANGEMENT REACTION of 3-ALKYLPHTHALIDES

THE REARRANGEMENT REACTION of 3-ALKYLPHTHALIDES

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摘要 The rearrangement of 3-butylphthalide and its two homologues to 5- carboxyl- 1 -alkyltetrahydronaphthalene by 1,4 - hydride transfer and 3- propytphthalide to 4-carboxyl-1 -alkylindane by 1,3-hydride transfer in the presence of AICI3 were observed and the possible mechanism was discussed. The rearrangement of 3-butylphthalide and its two homologues to 5- carboxyl- 1 -alkyltetrahydronaphthalene by 1,4 - hydride transfer and 3- propytphthalide to 4-carboxyl-1 -alkylindane by 1,3-hydride transfer in the presence of AICI3 were observed and the possible mechanism was discussed.

作者 SU Hua PANG Xiao Tian LIANG Zong Ru GUO Guang Zhong YANG(Institute of Materia Medica, Chinese Academy of Medial Sciencesand Peking Union Medical College, Beijing 100050)

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1994年第8期659-662,共4页 中国化学快报（英文版）

关键词 THE REARRANGEMENT REACTION of 3-ALKYLPHTHALIDES

分类号 O621.25 [理学—有机化学]

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Chinese Chemical Letters

1994年第8期

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