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CATALYTIC PROPERTIES OF SILICA-SUPPORTED POLY-γ-AMINOPROPYLSILOXANE-RHODIUM-COBALT BIMETALLIC COMPLEX FOR HYDROFORMYLATION

CATALYTIC PROPERTIES OF SILICA-SUPPORTED POLY-γ-AMINOPROPYLSILOXANE-RHODIUM-COBALT BIMETALLIC COMPLEX FOR HYDROFORMYLATION
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摘要 Hydroformylation of methyl methacrylate with a coneversion of 95.6% and selectivity of 92.8%for the normal product. methyl γ-formylisobutyrate has been achieved when the reactien was catalyzed by a silica-supported Poly-γ-aminopropylsiloxane-rhodium-cobalt bimetallic complex (abbreviated as SiO2- NH2-Rh-Co). The catalyst was Stable during the reaction and could be used repeatedly. Hydroformylation of methyl methacrylate with a coneversion of 95.6% and selectivity of 92.8%for the normal product. methyl γ-formylisobutyrate has been achieved when the reactien was catalyzed by a silica-supported Poly-γ-aminopropylsiloxane-rhodium-cobalt bimetallic complex (abbreviated as SiO2- NH2-Rh-Co). The catalyst was Stable during the reaction and could be used repeatedly.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1994年第6期531-532,共2页 中国化学快报(英文版)
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