HEATS　OF　INTERACTION　OF　ORGANIC　BASES　WITH　POLYMER　PROTECTED　CATALYST　PVC－AlCl＿3

HEATS OF INTERACTION OF ORGANIC BASES WITH POLYMER PROTECTED CATALYST PVC-AlCl_3

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摘要 Heats of immersion into a series of organic bases at 25℃ are reported for Polymer protected catalyst PVC-AlCl3. There is a good correlation between the heats of immersion of PVC-AlCl3 and thermochemical measurements of BF3 or SbCl5. The results have shown that the reaction of PVC-AlCl3 with various bases is essentially Lewis acid-base interaction and the surface acidity of PVC-AlCl3 is mainly attributed to Lewis acidity Heats of immersion into a series of organic bases at 25℃ are reported for Polymer protected catalyst PVC-AlCl3. There is a good correlation between the heats of immersion of PVC-AlCl3 and thermochemical measurements of BF3 or SbCl5. The results have shown that the reaction of PVC-AlCl3 with various bases is essentially Lewis acid-base interaction and the surface acidity of PVC-AlCl3 is mainly attributed to Lewis acidity

作者 Xiang Dong ZHANG Qi Tao LIU Wen Hua TAN Yu SONG (Department of Chemistry, Liaoning Universuty, Shenyang, 110036)

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1994年第6期533-536,共4页 中国化学快报（英文版）

关键词 PVC AlCl BASES

分类号 O643.32 [理学—物理化学]

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Chinese Chemical Letters

1994年第6期

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