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SYNTHESIS AND ̄(183)W NMR CHARACTERIZATI0N OF α-[P_2W_(15)O_(62)Ti_3] ̄(12-) HFTEROPOLYANION

SYNTHESIS AND  ̄(183)W NMR CHARACTERIZATI0N OF α-[P_2W_(15)O_(62)Ti_3] ̄(12-) HFTEROPOLYANION
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摘要 A trisubstituted Dawson anion,with tetravalent heteroelement titanium has been synthesized from the lacunary Precursor Na12[α-P2W15O56].24H2O and characterized by IR. UV.and 183W NMR Spectrum. 183W.NMR of the title ation consists of three lines(intensity ratio 1:2:2) as expected for the trisubstituted. Dawson anion. A trisubstituted Dawson anion,with tetravalent heteroelement titanium has been synthesized from the lacunary Precursor Na12[α-P2W15O56].24H2O and characterized by IR. UV.and 183W NMR Spectrum. 183W.NMR of the title ation consists of three lines(intensity ratio 1:2:2) as expected for the trisubstituted. Dawson anion.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1994年第6期547-548,共2页 中国化学快报(英文版)
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