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A NOVEL ARYL SHIFT IN THE OXIDATION OF ENOL SILYL ETHERS BY IODOSOBENZENE-BORON TRIFLUORIDE

A NOVEL ARYL SHIFT IN THE OXIDATION OF ENOL SILYL ETHERS BY IODOSOBENZENE-BORON TRIFLUORIDE
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摘要 The arylshiftwas found when the enol silyl ethers derived from 2-aryl-44chromanones and 3-aryl-l -tetralone were trealed with PhIO-BF3 ,yielding 3-aryl-chromanones and 2-aryl-3-fluoro-1-tetralones respectively, The rearrangement mechanism was suggested. The arylshiftwas found when the enol silyl ethers derived from 2-aryl-44chromanones and 3-aryl-l -tetralone were trealed with PhIO-BF3 ,yielding 3-aryl-chromanones and 2-aryl-3-fluoro-1-tetralones respectively, The rearrangement mechanism was suggested.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1994年第4期285-286,共2页 中国化学快报(英文版)
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