NEW　OSCILLATING　CHEMICAL　REACTIONS　WITH　THE　PARTICIPATION　OF　A　COPPER（Ⅱ）TETRAAZAMACROCYCLIC　COMPLEX

NEW OSCILLATING CHEMICAL REACTIONS WITH THE PARTICIPATION OF A COPPER(Ⅱ)TETRAAZAMACROCYCLIC COMPLEX

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摘要 Copper and nickel complexes with tetraazamacrocyclic ligands are shown to act as catalysts in Belousov-Zhabotinskii oscillating reactions. New oscillating reactions Via the oxidation of an unsaturated macrocyclic complex of copper(Ⅱ) by bromate ions in phosphoric acid medium have been discovered. Copper and nickel complexes with tetraazamacrocyclic ligands are shown to act as catalysts in Belousov-Zhabotinskii oscillating reactions. New oscillating reactions Via the oxidation of an unsaturated macrocyclic complex of copper(Ⅱ) by bromate ions in phosphoric acid medium have been discovered.

作者 Xiang Da ZHAO Zhi Qiang XU Liang ZHAO Ying Fang WANG Fu Xin XIE and Shi Sheng NI(Department of Chemistry, Anhui University, Hefei 230039)(National Key Lab. of Coord. Chem. in Nanjing Unly., Nanjing 210008)

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1994年第4期299-302,共4页 中国化学快报（英文版）

分类号 O614.121 [理学—无机化学]

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Chinese Chemical Letters

1994年第4期

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NEW　OSCILLATING　CHEMICAL　REACTIONS　WITH　THE　PARTICIPATION　OF　A　COPPER（Ⅱ）TETRAAZAMACROCYCLIC　COMPLEX

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NEW　OSCILLATING　CHEMICAL　REACTIONS　WITH　THE　PARTICIPATION　OF　A　COPPER（Ⅱ）TETRAAZAMACROCYCLIC　COMPLEX