摘要
本文主要涉及四个嘧啶化合物的合成,采用新的合成路线及新方法提高了主要中间产物的产率,在形成炔键时,使用二价钯作催化剂及应用快铜的方法是非常行之有效的。对化合物的SHG效应以及双炔化合物的固相聚合反应进行了研究。
Four novel pyridimine compounds were prepared. The yield of the intermediates was improved with new method making use of Pd(Ⅱ) catalyst and cuprous acetylide which were proved to be practital in the formation of the acetylide which were proved to be practical in the formation of the acetylides. Their nonlinear optical properties were briefly studied.