酸碱软硬度与△_rG_m~°的关系

The Relationship Betoeen △_rG_m° and the Degrees of the Hard and Sift Acids and Bases

通过对加合反应的亲强与吉布斯自由能变△G_m的计算,总结出两者之间的关系。目的在于把软碱酸碱理论推广到一般的加合反应中,使其成为一种新的判定化学反应方向的方法。

The attempt of the article is to caculate tne intimate degree of the addi- tive reactiom and the Gibbs free energ change (△_rG_m)from which the relation ship be- tween them may be deduced We are aim at applying the theiry of the Hard and soft acids and bases to a generd process of the additive reaction and make it a new method of judging chemical reactiom direction