摘要
Product operator formalism has been developed to evaluate, in closed analytical form, the time evolution for strongly coupled spin (I=1/2) systems. This formalismis based on two facts: (ⅰ) the Hamiltonian for a strongly coupled spin system is a zero-quantum operator and when an arbitrary zero-quantum operator acts on a p-quantum operator, what is yielded is still a p-quantum operator and can be expressed in terms of a linear combination of a complete p-quantum operator base set of the spin system; (ⅱ) the zeroquantum and unitary transformation leads the Hamiltonian to be only a linear combination of zero-quantum longitudinal magnetization and spin order operators. Thus the time evolution for the spin systems can be evaluated in closed analytical form. The formalism retains completely the original character of the product operator formalism and enlarges its applicability. It can deal with both strongly and weakly coupled spin (I=1/2) systems in united and closed analytical forms.
Product operator formalism has been developed to evaluate, in closed analytical form, the time evolution for strongly coupled spin (I=1/2) systems. This formalismis based on two facts: (ⅰ) the Hamiltonian for a strongly coupled spin system is a zero-quantum operator and when an arbitrary zero-quantum operator acts on a p-quantum operator, what is yielded is still a p-quantum operator and can be expressed in terms of a linear combination of a complete p-quantum operator base set of the spin system; (ⅱ) the zeroquantum and unitary transformation leads the Hamiltonian to be only a linear combination of zero-quantum longitudinal magnetization and spin order operators. Thus the time evolution for the spin systems can be evaluated in closed analytical form. The formalism retains completely the original character of the product operator formalism and enlarges its applicability. It can deal with both strongly and weakly coupled spin (I=1/2) systems in united and closed analytical forms.
