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The isotopic effects in the IR-multiphoton excitation of molecules with c_(2v) symmetry

The isotopic effects in the IR-multiphoton excitation of molecules with c_(2v) symmetry
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摘要 Quantum dynamical calculations for the IR-multiphoton excitation of H_2O,D_2O and T_2O are presented using a generalized Hamiltonian for XY_2 molecules.The energy spectra obtained from this Hamiltonian are in good agreement with those of the experiments.The long time average of the transition probabilities and the isotopic effects are discussed in detail, Quantum dynamical calculations for the IR-multiphoton excitation of H_2O,D_2O and T_2O are presented using a generalized Hamiltonian for XY_2 molecules.The energy spectra obtained from this Hamiltonian are in good agreement with those of the experiments.The long time average of the transition probabilities and the isotopic effects are discussed in detail,
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1993年第4期321-328,共8页 中国化学(英文版)
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