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Study of the vibrational photochemical reation of UF_6+HCl and its isotopic selectivity

Study of the vibrational photochemical reation of UF_6+HCl and its isotopic selectivity
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摘要 The photochemical vibrational reaction of UF_6+HCl was investigated by exciting the ternary overtone of 3ν_3 of UF_6 in an intracavity CO laser system.It was found that the rate of the laser-driven reaction was much greater than that of the thermal reaction and this photochemical process had an isotopic selectivity.The uranium isotope enrichment factors measured in experiments wore around 1,007 in a single step. The photochemical vibrational reaction of UF_6+HCl was investigated by exciting the ternary overtone of 3ν_3 of UF_6 in an intracavity CO laser system.It was found that the rate of the laser-driven reaction was much greater than that of the thermal reaction and this photochemical process had an isotopic selectivity.The uranium isotope enrichment factors measured in experiments wore around 1,007 in a single step.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1993年第2期97-104,共8页 中国化学(英文版)
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