期刊文献+

Nitrosyl Complexes 6.Reactions of Na[Fe(CO)_3NO]with Cp~*M(CO)_3Cl(Cp~*=η~5-CH_3C_5H_4,M=Mo or W):Crystal structures of Cp~*M(CO)_2NO and Cp~*M(μ_3-NH)(μ_2-NO)(μ_2-CO)Fe_2(CO)_6

Nitrosyl Complexes 6.Reactions of Na[Fe(CO)_3NO]with Cp~*M(CO)_3Cl(Cp~*=η~5-CH_3C_5H_4,M=Mo or W):Crystal structures of Cp~*M(CO)_2NO and Cp~*M(μ_3-NH)(μ_2-NO)(μ_2-CO)Fe_2(CO)_6
全文增补中
导出
摘要 Sodium nitrosylcarbonyliron reacts with methylcyclopentadienylcarbonylmetal(Mo orW)chloride in CHOH/THF at room temperature to give CpMo(CO)NO(1a)(Cp=η-CHCH)or CpW(CO)NO(1b),[CpMo(CO)](2a)or[CpW(CO)](2b),and CpMo(μ3-NH)(μ2-NO)-(μ2-CO)Fe(CO)(3a)or CpW(μ3-NH)(μ2-NO)(μ2-CO)Fe(CO)(3b),respectively.Complexes1a,1b,3a and 3b were analyzed by IR,NMR,MS and elemental analyses,and the crystalstructures of 1b,3a and 3b were determined by X-ray diffraction method.The new clusters 3aand 3b have μ3-NH ligands which were formed by redaction of NO in the synthetic reactions.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1993年第2期151-158,共8页 中国化学(英文版)
  • 相关文献

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部