STUDY ON THE INTRAMOLECULAR CVCLIZATION THROUGH OPENING OF EPOXIDE II RING CLOSURE OF N-METHYL-N-BENZOYLMETHYLENE-β-PHENYL-α,β-EPOXYPROPIONAMIDE IN PROTIC SOLVENT
STUDY ON THE INTRAMOLECULAR CVCLIZATION THROUGH OPENING OF EPOXIDE II RING CLOSURE OF N-METHYL-N-BENZOYLMETHYLENE-β-PHENYL-α,β-EPOXYPROPIONAMIDE IN PROTIC SOLVENT
摘要
When the title compound was treated in protic solvent with alkali catalyses,γ-lacatam was almost the sole product.The ratio of ketone 1 to ketone 2 depended upon the reaction condition.
When the title compound was treated in protic solvent with alkali catalyses,γ-lacatam was almost the sole product.The ratio of ketone 1 to ketone 2 depended upon the reaction condition.
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1Guang Zhong YANG Li Hong WANG Liang HUANG Institute of Matena Medica,Chinese Academy of Medical Sciences ■Xian Nong Tan St,Beijing,100050.STUDY ON THE INTRAMOLECULAR CYCLIZATION THROUGH OPENING OF EPOXIDE I CYCLIZATION OF N-METHYL-N-BENZOYLMETHYLENE-β-PHENYL-α,β-EPOXYPROPIONAMIDE IN APROTIC SOLVENT[J].Chinese Chemical Letters,1993,4(12):1035-1036.
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2WEI,Xu-Dong HU,Hong-Wen HU,Yue-Fei Department of Chemistry,Nanjing University,Nanjing 210008JIN,Yong-Shu JIN,Tong-Zheng HAN,Shi-Ying XU,Yun-Xia The Centre of Materials analysis,Nanjing University,Nanjing 210008.Dehydrodimers of arylaldoxime——a convenient source of iminoxy radicals[J].Chinese Journal of Chemistry,1992,10(4):344-349. 被引量:1
-
3曲雅焕,王晓菊,于薇,李玉良,于广谦.Synthesis,Characterization and Catalytic Activity of Propionamide Complexes of Rare Earth Chlorides[J].Journal of Rare Earths,1998,16(4):23-26.
-
4WU Cheng-pei,PAN Cai-yuan,Toshiyuki Uryu.Syntheses of Cellulose-Type Polysaccharide by Means of Ring-Opening Copolymerization of Anhydroriboses ABRP and AIRP[J].Chemical Research in Chinese Universities,1998,14(2):86-90.
-
5DENG Yan Shanghai Institute of Organic Chemistry,Academia Sinica,Shanghai.Study on the mechanism of Schiemann reaction by mass spectrometry[J].Acta Chimica Sinica English Edition,1989,7(5):422-430.
-
6Ji Ben MENG Wen Guang WANG Yong Mei WANG Hong Gen WANG Department of Chemistry and Central Laboratory,Nankai University Tianjin 300071.SOLID STATE PHOTOREACTION OF N-HETERO-CYCLIC COMPOUNDS[J].Chinese Chemical Letters,1993,4(2):115-118.
-
7Wu Yan ZHANG,Ji Yu GUO,Xiao Tian LIANG.Studies on Agarofurans V. Studies on the Reductive Ring-Opening of 3,4-Epoxide of Agarofurans[J].Chinese Chemical Letters,2000,11(12):1041-1044.
-
8Zhi Yu LIU Jian Jun ZHANG Wei CHEN Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,345 Lingling Lu,Shanghai 200032.A FACILE SYNTHESIS OF(±)-MURICATAIN[J].Chinese Chemical Letters,1993,4(8):663-664.
-
9Epoxide Based Asymmetric Synthesis[J].厦门大学学报(自然科学版),1999,38(S1):228-228.
-
10Tianbao Li,Xinhai Li,Kexiong Huang,Hanying Jiang,Jing Li.SYNTHESIS AND CHARACTERIZATION OF HYDROXYLATED FULLERENE EPOXIDE—AN INTERMEDIATE FOR FORMING FULLEROL[J].Journal of Central South University,1999,11(1):36-37. 被引量:2