摘要
A new dimolybdenum(V)complex[(C_6H_4Cl)_2C(Ph)]_2[Mo_2(μ-Cl)_3Cl_4O_2][Mo_2(μ- Cl)_2Cl_4O_2(μ-OCOPh)]has been obtained in the reaction of PhCl with benzoyl peroxide (PhCO_2)_2 and MoCl_5.Its crystal structure has been determined by X-ray diffraction meth- ods.Spectroscopic characterization of the compound and ASED-MO calculation of the trityl cation are reported.
A new dimolybdenum(V)complex[(C_6H_4Cl)_2C(Ph)]_2[Mo_2(μ-Cl)_3Cl_4O_2][Mo_2(μ- Cl)_2Cl_4O_2(μ-OCOPh)]has been obtained in the reaction of PhCl with benzoyl peroxide (PhCO_2)_2 and MoCl_5.Its crystal structure has been determined by X-ray diffraction meth- ods.Spectroscopic characterization of the compound and ASED-MO calculation of the trityl cation are reported.
