摘要
This paper presents the synthesis and structural characterization of asymmetric tripyrrane-containing macrocycle.This macrocycle could be oxidized to the methine bridged,22 π-electron aromatic macrocyclic complexes containing cadmium(Ⅱ),samarium (Ⅲ),europium(Ⅲ)and gadolinium(Ⅲ)by treating with corresponding metal chloride in the presence of air Their structures were characterized by spectral methods.
This paper presents the synthesis and structural characterization of asymmetric tripyrrane-containing macrocycle.This macrocycle could be oxidized to the methine bridged,22 π-electron aromatic macrocyclic complexes containing cadmium(Ⅱ),samarium (Ⅲ),europium(Ⅲ)and gadolinium(Ⅲ)by treating with corresponding metal chloride in the presence of air Their structures were characterized by spectral methods.
基金
This work was supported by NSFC.
