GAS-PHASE ION-MOLECULE REACTIONS OF BUCKMINSTERFULLERENE(C_(60))WITH Si(CH_3)_n CL_(4-n)(n=2,3)IN MASS SPECTROMETER

GAS-PHASE ION-MOLECULE REACTIONS OF BUCKMINSTERFULLERENE(C_(60))WITH Si(CH_3)_n CL_(4-n)(n=2,3)IN MASS SPECTROMETER

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摘要 Reactions of C60 with Si(CH_3)_nCl_(4-n) (n=2,3)in the ion source of the mass spectrometer have been studied.The corresponding adduct ions[C60Si(CH_3)_mCl3_(-m)]^+(m=1,2,3),[C60SiCl]^+ and[C60CH_3]^+ were observed and their possible structures were discussed.The results indicated that C60 is very reactive to electrophiles in the gas phase. Reactions of C60 with Si(CH_3)_nCl_(4-n) (n=2,3)in the ion source of the mass spectrometer have been studied.The corresponding adduct ions[C60Si(CH_3)_mCl3_(-m)]^+(m=1,2,3),[C60SiCl]^+ and[C60CH_3]^+ were observed and their possible structures were discussed.The results indicated that C60 is very reactive to electrophiles in the gas phase.

作者 Xing Hua GUO Zi Yang LIU Shu Ying LIU Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,130022

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第9期797-800,共4页 中国化学快报（英文版）

关键词 n=2 3)IN MASS SPECTROMETER WITH Si CH3 n CL N ION CL GAS-PHASE ION-MOLECULE REACTIONS OF BUCKMINSTERFULLERENE SICI

分类号 O6 [理学—化学]

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Chinese Chemical Letters

1993年第9期

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GAS-PHASE ION-MOLECULE REACTIONS OF BUCKMINSTERFULLERENE(C_(60))WITH Si(CH_3)_n CL_(4-n)(n=2,3)IN MASS SPECTROMETER

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