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Study of Reactivity of Oxygen Species on SmMO_3(M=Mn,Fe)by TDS and TPRS

Study of Reactivity of Oxygen Species on SmMO_3(M=Mn,Fe)by TDS and TPRS
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摘要 With O_2 and CO as the molecular probes,the reactivity of oxygen species of perovskite-like oxides SmMnO_3 and SmFeO_3 was studied by thermodesorption spectroscopy(TDS)and temperature- programmed reaction spectroscopy(TPRS)in an ultrahigh vacuum system.The results of the experiment implied that the oxidation of CO on SmMO_3 may follow Langmuir-Hinshelwood mechanism. With O_2 and CO as the molecular probes,the reactivity of oxygen species of perovskite-like oxides SmMnO_3 and SmFeO_3 was studied by thermodesorption spectroscopy(TDS)and temperature- programmed reaction spectroscopy(TPRS)in an ultrahigh vacuum system.The results of the experiment implied that the oxidation of CO on SmMO_3 may follow Langmuir-Hinshelwood mechanism.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 1993年第1期63-65,共3页 稀土学报(英文版)
关键词 SmMnO_3 SmFeO_3 TDS TPRS Oxygen species SmMnO_3 SmFeO_3 TDS TPRS Oxygen species
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