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Hydrogen Sensing Property of Lanthanum Complex Fluoride

Hydrogen Sensing Property of Lanthanum Complex Fluoride
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摘要 Four potentiometer sensor cells have been prepared by using La0.95Pb0.05F2.95 as solid electrolyte(SE) and various materials as electrodes. The sensor cell `Bi(BiF3)|SE|Pt' exhibits the best performance with its 90% response time as short as 75 s to 100 Pa H2 in air at room temperature and with its linear decrease of electromotive force (EMF) with an increase of the logarithm of hydrogen partial pressure in the experimental range. The sensor cell shows weaker response to CO. Four potentiometer sensor cells have been prepared by using La0.95Pb0.05F2.95 as solid electrolyte(SE) and various materials as electrodes. The sensor cell `Bi(BiF3)|SE|Pt' exhibits the best performance with its 90% response time as short as 75 s to 100 Pa H2 in air at room temperature and with its linear decrease of electromotive force (EMF) with an increase of the logarithm of hydrogen partial pressure in the experimental range. The sensor cell shows weaker response to CO.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 1993年第2期115-119,共5页 稀土学报(英文版)
基金 This project was supported by the National Natural Science Foundation of China Laboratory of Rare Earth Chemistry and Physics,Chinese Academy of Sciences
关键词 Electric field effects Fluorine compounds Gas sensing electrodes HYDROGEN Pressure effects Solid electrolytes Thermal effects Electric field effects Fluorine compounds Gas sensing electrodes Hydrogen Pressure effects Solid electrolytes Thermal effects
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