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EFFECT OF STRUCTURE PARAMETERS OF POLYESTER ON ITS ALKALI REACTION RATE

EFFECT OF STRUCTURE PARAMETERS OF POLYESTER ON ITS ALKALI REACTION RATE
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摘要 The effect of the supermoleclar structure of polyester on the effective alkali hy-drolysisis rate constant k has been investigated in the paper.That the average non-crvstal line volume around per crystal grain has a close relation to the k is proved byexperiments.A simple and effctive method for assessing what effect of the super-molecular structure on the k by its CDT value( Critical Dissolution Time) has beenput forward. The effect of the supermolecular structure of polyester on the effective alkali hy-drolysisis rate constant k has been investigated in the paper. That the average non -crystal line volume around per crystal grain has a close relation to the k is proved by experiments. A simple and effctive method for assessing what effect of the super-molecular structure on the k by its CDT value (Critical Dissolution Time) has been put forward.
作者 武谦
出处 《苏州大学学报(工科版)》 CAS 1993年第S2期45-53,共9页 Journal of Soochow University Engineering Science Edition (Bimonthly)
关键词 Supermolecutar structure . CRYSTALLINITY CDT Value Non - crystal volume. ALKALI HYDROLYSIS rate CON -stant. Supermolecutar structure . Crystallinity CDT Value Non - crystal volume. Alkali hydrolysis rate con -stant.
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