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THE SYNTHESIS OF CROSS-LINKED POLYSTYRENE RESINS GRAFTED BY L-PROLINE THROUGH HYDROPHILIC SPACERS

THE SYNTHESIS OF CROSS-LINKED POLYSTYRENE RESINS GRAFTED BY L-PROLINE THROUGH HYDROPHILIC SPACERS
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摘要 L-proline was linked onto cross-linked polystyrene to give chiral chelating resin (1). The copper (Ⅱ) chelate of resin (1) was used as the chiral stationary phase for the chromatographic resolution of DL-amino acids. However, the hydrophobicity of polystyrene causes an amino acid to transfer slowly during chromatographic process so <正> L-proline was linked onto cross-linked polystyrene to give chiral chelating resin (1). The copper (Ⅱ) chelate of resin (1) was used as the chiral stationary phase for the chromatographic resolution of DL-amino acids. However, the hydrophobicity of polystyrene causes an amino acid to transfer slowly during chromatographic process so that
出处 《Chinese Science Bulletin》 SCIE EI CAS 1990年第7期554-557,共4页
关键词 chiral CHELATING resin LIGAND-EXCHANGE chromatography resolution of DL-amino acids. chiral chelating resin, ligand-exchange chromatography, resolution of DL-amino acids.
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